(2,2′-Bipyrimidine-κ2 N 1,N 1′)bis(thiocyanato-κN)platinum(II)
نویسنده
چکیده
In the title complex, [Pt(NCS)(2)(C(8)H(6)N(4))], the Pt(II) ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2'-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN(-) anions. The thio-cyanate ligands are almost linear, displaying N-C-S bond angles of 178.6 (11) and 173.7 (11)°, and the N atoms are slightly bent coordinated to the Pt atom with Pt-N-C bond angles of 172.7 (9) and 160.4 (10)°. In the crystal, mol-ecules are held together by C-H⋯S hydrogen bonds. Intra-molecular C-H⋯N hydrogen bonds are also observed.
منابع مشابه
Dipotassium tetrakis(thiocyanato-κS)palladate(II)–(2,2′-bipyrimidine-κ2 N 1,N 1′)bis(thiocyanato-κS)palladium(II) (1/2)
The asymmetric unit of the title compound, K(2)[Pd(NCS)(4)]·2[Pd(NCS)(2)(C(8)H(6)N(4))], contains two crystallographically independent half-mol-ecules of the anionic Pd(II) complex, two K(+) cations and two independent neutral Pd(II) complexes; an inversion centre is located at the centroid of each anionic complex. In the anionic complexes, each Pd(II) ion is four-coordinated in an almost regul...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012